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Главная страница > Энциклопедический словарь Железнова, страница 152 > Гидролиз

Гидролиз

Гидролиз. Соли 1) слабых кислот с сильными основаниями, 2) сильных кислот со слабыми основаниями и 3) слабых кислот со слабыми основаниями подвергаются при действии воды разложению на соответствующия кислоту и основание. Это явление разложения солей водою называется Г. Для первых двух групп солей это явление легко может быть замечено по отношению их растворов к лакмусу. Обыкновенно растворы средних солей (о средних, кисл. и основн. солях см. соли), как хлористый натрий (NaCl) и тому подобное., не окрашивают лакмуса ни в синий, ни в красный цвет; они, как говорят, нейтральны по отношению к лакмусу. Растворы же указанных только что групп солей окрашивают лакмуслибо в синий, либо в красный цвет. Так, наприм., раствор цианистого калия KCN (калиев. соль синильной кислоты) окрашивает лакмус в синий цвет, т. е. обладает щелочной реакцией, — характерным признаком растворов оснований. Эта соль гидролизуется (разлагается водой) по уравнению: KCN+H20=KOH+HCN. В растворе появляется очень сильное основание, едкое кали (КОН), наряду с очень слабой синильной кислотой (HCN). Следовательно, в растворе будут преобладать основныя—щелочные — свойства, и лакмус окрасится им в синий цвет. Раствор хлорного железа РеС13 (железн. соль соляной кислоты) обладает сильной кислотной реакцией. Соль эта разлагается водой: FeCl3 + ЗН30=Ре(0Н)3 + ЗНС1; появляющаяся при этом разложении соляная кислота НС1 и придает кислотную реакцию раствору хлорного железа.

Г. представляет собою процесс, обратный нейтрализации, т. е. образованию соли из кислоты и основания; при этом последнем процессе из основания и кислоты получаются соль и вода, при Г. из соли и воды—основание и кислота; нейтрализация: HCN-b 4-КОН=KCN + Н„0; Г.: KCN + Н20== H.CN + K0H. “

Такие процессы, как нейтрализация слабых кислот сильными основаниями, сильных кисл. слабыми осн. и слаб. кисл. слаб. осн., и Г. соответствующих солей, — называются обратимыми. Они могут идти как в ту, так и в другую сторону, что обозначают так: HCN+K0H=KCN-f-H20; но ни в ту, ни в другую сторону они не идут до конца; при нейтрализации синильной кислоты едким кали, не все их частицы перейдут в частицы цианистого калия и воды, и обратно, при Г. цианистого калия не все его частицы перейдут в синильн. кисл. и едкое кали. В обоих случаях, в конце концов, будут находиться в растворе все четыре вещества в одних и тех же отношениях (смотрите равновесие химич.).

Легче всего подвергаются Г. соли слабых кислот со слабыми основаниями. Совсем не подвергаются Г. (приобычных условиях) соли сильных кислот с сильными основаниями.

Степень гидролитического расщепления соли увеличивается с повышением температуры. Так, если нагревать разбавленный почти до обезцве-чивания раствор хлорного железа, то он становится красноватобурым от появления больших сравнительно с прежним количеств гидроокиси железа Ре(ОН)3, как следствия увеличенной с повышением температуры степени гидролит. расщепления хлорного железа.

Явления Г. становятся вполне понятными, вполне объяснимыми во всех своих подробностях при применении к ним теории электролитической диссоциации. JI. Писаржевскгй.